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The hydrogenation of heterocyclic calix[4]arenes, a transformation leading to novel macrocyclic ligands

Auteur(s)
Jones, Christopher R.
Blangy, Valeria
Date de parution
2012
In
Heterocycles
Vol.
4
No
85
De la page
749
A la page
797
Mots-clés
Résumé
A review. Hydrogenation reactions of calix[4]furan and calix[4]pyrrole were reviewed together with the authors' own work in this field. A short description of the metal binding process of our new calix[4]pyrrolidines (= the fully satd. calix[4]pyrrole) with Cu was discussed as a typical example of the metal binding capacities. The new calix[4]pyrrolidines can be structurally classified as new stiffened macrocyclic crown ethers or as satd. analogs of the porphyrin-derived "pigments of life". [on SciFinder(R)]
Identifiants
https://libra.unine.ch/handle/123456789/21460
Type de publication
journal article